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#1 Posted : 05 October 2006 15:10:00(UTC)
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Posted By Tina Hansen Hello, We are currently searching for a product to replace the use of trichloroethylene in our facility. We are currently using it for as a quick-drying cleaner for machines in the metal industry. We are/have tried several products which seem to be almost as toxic or extremely flammable. Does anyone of a good alternative? Best regards Tina
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#2 Posted : 05 October 2006 15:47:00(UTC)
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Posted By Darby Allan Hi V quick search on google with Trichloroethylene substitute as key words came up with quite a few. http://www.eurochlor.org/qandatrienglish This looked quite interesting. Regards Darby
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#3 Posted : 09 October 2006 10:19:00(UTC)
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Posted By Diane Thomason Hi Tina, I just found this: http://www.cleanersolutions.org/ If you click on find a replacement, you can select the solvent you currently use and what you use it for, i.e. process and materials, and the database suggests alternatives. Looks like it could be useful. Cheers Diane
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#4 Posted : 09 October 2006 10:54:00(UTC)
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Posted By Chris Packham Tina Much will depend upon the actual nature of the operation. In some cases it is possible to dispense with solvents and detergents completely. For example, it is possible to clean ink of rollers on printing presses using dry ice. Equally, where it is unavoidable that a quick-drying solvent is used, it may be possible to adapt/modify the process to reduce actual or potential exposure. If you feel I might be able to help, give me a call (01386 832 311) Chris
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#5 Posted : 09 October 2006 11:20:00(UTC)
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Posted By Alexander Falconer I was faced with the same problem some years ago, whilst working for an engineering company in Scotland. We went for an environmentally friendly substitute called citrosol, which was a citrus based, it was an adequate degreasing cleaner, but not as good as trike. Supplier was a D Fraser & Co in Hamilton, 01698 459003. Why not give them a call and see what they could do for you (or at least point you in the right dirsction) Alex
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#6 Posted : 09 October 2006 11:57:00(UTC)
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Posted By Chris Packham Re citrus based degreasants: 1. Be aware that they are still skin irritants. Whilst they may not present the same problems as trike, skin exposure must be carefully controlled. The main base is a terpene called d-limonene. This is a hydrocarbon (C10H16). 2. Whilst these citrus based degreasants are not sensitisers as supplied, there is abundant evidence that, exposed to the air, oxidisation takes place. This can result in contaminants that are potent sensitisers. Indeed, some can be photo-sensitisers, i.e. make you permanently ultrasensitive to UV. They are, of course, less volatile, and therefore perhaps easier to control than the petroleum-based products, but they are not without their own risks. If anyone needs more on this, contact me direct. Chris
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#7 Posted : 09 October 2006 12:25:00(UTC)
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Posted By AJM Hi, I myself went through this process 10 months ago and did get a replacement which has served us well If you would like any info please e-mail me direct. To answer you Chris. Yes we used the citrus based product that worked well and was more cost effective and last but most importantly, yes it is an irritant but its better to substitute it for that rather than the toxic and cancerous Trichloroethylene. Alan
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#8 Posted : 09 October 2006 12:39:00(UTC)
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Posted By Alexander Falconer I'll second that too! Would rather be suffering from irritated skin rather than cancer! Having stated the citrus based substances, there may well be others just as good that have came into the market within the last 5 years (since I last had dealings with the subject)
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#9 Posted : 09 October 2006 12:41:00(UTC)
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Posted By Chris Packham Alan I entirely agree with you. The point I was concerned about is that these products are sometimes promoted as "safe" or "natural", with the implication that they do not present any hazards to health. What I hoped my posting indicated is that even these products need to be treated with caution. I have had cases with clients where oxidised citrus oil has resulted in occupational allergic contact dermatitis. In all cases the client was unaware of the change that could occur to create the sensitiser, nor was this indicated on the safety data sheet. Chris
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#10 Posted : 09 October 2006 18:12:00(UTC)
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Posted By AJM Right I get you now Chris, And your points are very interesting.
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#11 Posted : 09 October 2006 18:52:00(UTC)
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Posted By JWG Why whats wrong with Trichloroethylene? When I worked for a furniture foam company we used to wash our hands in it. I now know it's nasty stuff. It's probably the main culprit as to why many staff were forced to retire or sacked because they failed the peak expiratory flow test.
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#12 Posted : 10 October 2006 09:58:00(UTC)
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Posted By Ali There are 2 issues here : protecting Health & Safety and protecting the Environment. Ideally, you need a solvent that can do the same job without being more hazardous, but at the same time is not injurious to the atmosphere / ozone layer. The simplest of all solvents is alcohol, but it may not be as effective as Tric, though it is much cheaper to use and there is little evidence that it destroys the ozone layer. Also, it is less flammable. The next solvent could be an isomer of alcohol such as isopropanol or similar and so on. There is also acetone, but this has H&S implications, which is why chemists are phasing out it's use in shops. Anyone out there with a reasonably good knowledge of organic chemistry ? Maybe the Environment Agency can advise as there is also legislation about what waste you can and cannot discharge.
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#13 Posted : 10 October 2006 10:05:00(UTC)
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Posted By Chris Packham Does it actually have to be a chemical? As an example, it is possible to remove printing ink from rollers on presses using dry ice and compressed air. No solvents, no flammable substances, much reduced volume of waste to dispose of etc. The same technique can be used to clean machinery, remove anti-fouling from boats etc. In kitchens it is now common to find steam, without any chemical additive, being used to clean cooker hoods etc. Perhaps we need to "think outside the box" and, at least, keep ourselves informed as to what alternatives appear from time to time. Chris
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#14 Posted : 10 October 2006 10:13:00(UTC)
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Posted By Dave Wilson Marky s markeys back!
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#15 Posted : 10 October 2006 10:28:00(UTC)
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Posted By Jeffrey Watt Chris Some great points. We used dry ice shot blasting to clean equipment with caked on polish slurry. As the dry ice sublimes to gas the velocity drops off within Cm's of the area (so no nasty projectile hazards) you are blasting with no grit and no residue. Oxygen depletion was non existent when measured in our scenario as general ventilation was adequate in the large work area. General clean down of oil based coolant on our lathes and robots was done with 30% Isopropyl alcohol soaked polypropylene wipes (like baby wipes in appearence), disposed of as flammable rags in FM approved bins. IPA was effective and in 5 years no detected problems in occ health. Just on baby wipes, I have used them to get selotape residue off windows (when white spirits, vinegar, windowlene and razor blades couldn't shift it) and remove oil out of carpet. Kind regards Jeff
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#16 Posted : 10 October 2006 10:39:00(UTC)
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Posted By Chris Packham Jeff Very interesting and just confirms my thoughts that sometimes we don't always look to see what alternatives there are for us. However.... From what you have written I don't think I will ever use a baby wipe on a baby again! Chris
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#17 Posted : 10 October 2006 10:53:00(UTC)
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Posted By Jeffrey Watt Yeah Chris,you should see the shine on the dog.
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