Welcome Guest! The IOSH forums are a free resource to both members and non-members. Login or register to use them

Postings made by forum users are personal opinions. IOSH is not responsible for the content or accuracy of any of the information contained in forum postings. Please carefully consider any advice you receive.

Notification

Icon
Error

Options
Go to last post Go to first unread
Admin  
#1 Posted : 19 February 2008 15:04:00(UTC)
Rank: Guest
Admin

Posted By Dave Morris I have recently measured an airborne contaminant involving hydrocarbons, specifically Alkanes. My measurement is in PPM but EH40 (page 52) suggests a guidance value of 1200mg/m3 for alkanes. My problem therefore is the need to convert mg/m3 to ppm. For my online conversion calculator I require the molecular weight of Alkanes, for this I require the chemical formula for Alkanes so I can add the atomic weights of all atoms present in the chemical formula. The manufacturer has not specified this chemical formula on the safety data sheet. Does anyone know of another way (other than sampling in mg/m3) that I can find out these molecular weights?
Admin  
#2 Posted : 19 February 2008 15:26:00(UTC)
Rank: Guest
Admin

Posted By Paul Leadbetter Dave You do need to know the molecular weight but I guess you are dealing with a mixture; does the CAS number, or the boiling point range, enable you to make an educated guess at the main constituents? Paul
Admin  
#3 Posted : 19 February 2008 15:46:00(UTC)
Rank: Guest
Admin

Posted By Adrian Watson Dave, Unfortunately, you cannot convert between the two unless you have either a full and complete analysis of the material sampled by GCMS or know the average molecular weight. The Molecular Weights can be obtained from a chemistry database or textbook. Regards Adrian
Admin  
#4 Posted : 19 February 2008 16:11:00(UTC)
Rank: Guest
Admin

Posted By Robert K Lewis If you consider the alkane series they have the same general formula: C(X)H(2X+2)where X is the number of carbon atoms Below 4 the alkanes are generally gases eg Methane (CH4), and above 4 they are liquid eg Pentane,hexane, heptane, octane. Above 16 they become solids. The most likely to be used are 5, 6 and 7 carbon atoms if this is vaporised liquid so you could work on a molecular weight of 86 as a first approximation. If this is from a gaseous source at room temperature then use a figure of 44 as a first approximation Bob
Admin  
#5 Posted : 19 February 2008 16:16:00(UTC)
Rank: Guest
Admin

Posted By Dave Morris Paul, the CAS no is 90622-57-4 with a 50-100% concentration. The boiling point is 173C. How does this help me?
Admin  
#6 Posted : 19 February 2008 16:34:00(UTC)
Rank: Guest
Admin

Posted By Jane Blunt That CAS no. appears to belong to a mixture C9 to C12, which if my arithmetic is correct gives a molecular weight in the range 128 to 170. Jane
Admin  
#7 Posted : 19 February 2008 16:41:00(UTC)
Rank: Guest
Admin

Posted By Paul Leadbetter Dave From the CAS number, your solvent mixture is otherwise known as Isopar G which, if memory serves me correctly, is a mixture of C10 - C11 alkanes and cycloalkanes. The boiling point of n-decane is 174ÂșC which fits closely with the bp you quote. The methylnonanes boil at 165 - 168, the dimethyloctanes at 155 - 161 and undecane at 196. In the absence of compositional data (although you may be able to find that on the internet), you can get a rough conversion by assuming that the solvent is n-decane. Paul
Admin  
#8 Posted : 19 February 2008 16:42:00(UTC)
Rank: Guest
Admin

Posted By Robert K Lewis Shows the importance of getting all available information Nonane, decane and dodecane are a little esoteric though for me. I think I will stick with teh aromatics as I am more at home in their presence. Dave What process is this that you are emitting measurable vapours from relatively non-volatile materials? Bob
Admin  
#9 Posted : 19 February 2008 16:52:00(UTC)
Rank: Guest
Admin

Posted By Dave Morris Bob It's a close loop solvent degreasing process where the hydrocarbon is heated in an ultrasonic bath. I believe the chiller unit is malfunctioning and I wanted to ensure we didn't exceed any WEL's.
Admin  
#10 Posted : 19 February 2008 20:12:00(UTC)
Rank: Guest
Admin

Posted By Adrian Watson You have also added another complication. The formula in EH40 is for 20 C, so will need correcting. Regards Adrian
Users browsing this topic
Guest
You cannot post new topics in this forum.
You cannot reply to topics in this forum.
You cannot delete your posts in this forum.
You cannot edit your posts in this forum.
You cannot create polls in this forum.
You cannot vote in polls in this forum.