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#1 Posted : 20 February 2008 12:13:00(UTC)
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Posted By Chris Packham
I have posted concerns about the use of Material Safety Data Sheets for COSHH risk assessments on several occasions on this forum.

Investigating a suspected case of occupational skin disease for a client yesterday I was presented with a safety data sheet for a cleaning fluid that the employee used. Section 16 of this safety data sheet contained the following statement:

“The information relates to the specific product designated and may not be valid if it is used in combination with other materials or process.” (Incidentally, nowhere on the safety data sheet is a “process” defined.)

Question 1:- How is one going to use a cleaning fluid without it coming into contact and absorbing other materials?

The Health and Safety at Work etc. Act 1974, Section 6-1, imposes a duty on the supplier:

“It shall be the duty of any person who designs, manufactures, imports or supplies any article for use at work –
(c) to take such steps as are necessary to secure that there will be available in connection with the use of the article at work adequate information about the use for which it is designed and has been tested, and about any conditions necessary to ensure that, when put to that use, it will be safe and without risks to health.

Question 2:- Given the statement in the safety data sheet how can the supplier claim that he has complied with Section 6-1?

Question 3:- How many of your safety data sheets contain a similar clause and what are the implications if you rely upon the information in the safety data sheet for your risk assessment?

Chris
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#2 Posted : 20 February 2008 12:25:00(UTC)
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Posted By Paul Leadbetter
I agree with you, Chris, but the situation will not improve until someone is prosecuted for distributing an inadequate MSDS.

Paul
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#3 Posted : 20 February 2008 12:57:00(UTC)
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Posted By anon1234
Agree with your concerns - it doesn't help that a lot of people refer to an MSDS as a CoSHH sheet or similar.

Clearly an MSDS is NOT a CoSHH assessment but I have come across far too many 'health and safety professionals' (?!?) who think they are one in the same. Which links to one of my pet subjects - competence of those giving advice. there are too many people who are willing to wing it in our profession and we need to do something about this. Although I don't subscribe wholly to the theories such as 'you arn't competent unless you are CMIOSH' - and by the way I am CMIOSH so I'm not arguing against it because I haven't got 'it'. I (hopefully) recognise when I don't have the right competencies to undertake something/provide advice on something and think we need to encourage this 'self-assessment' approach more.
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#4 Posted : 20 February 2008 13:06:00(UTC)
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Posted By Chris Packham
The following example may help to explain why I am so concerned about the information that suppliers are providing and the unsuitability of our present safety data sheet. Last year I had to investigate a suspected case of occupational contact dermatitis. The product in question was a pre-impregnated carbon fibre sheet. The safety data sheet indicated that the impregnation contained a high level of tetraglydicyl methylenedianiline, listed as R43, i.e. a skin sensitiser.

However, subsequent investigation showed that so little of this was being released during normal use that it was below the exposure level needed to elicit an allergic reaction, far less cause sensitisation.
In fact, the claim of skin allergy to the chemical was not valid, so no occupational skin problem, no RIDDOR report, no compensation claim, etc.

Whilst the information on the safety data sheet indicated a substance with a significant hazard, in this case the opposite was true.
Of course, if the fibre sheet were to have been treated as part of the process with a solvent the problem would have been quite different.

So how does the "non-specialist", which will include most small enterprises, interpret the information suppliers are giving them?

Chris
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#5 Posted : 20 February 2008 13:13:00(UTC)
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Posted By Chris G
I've also come across suppliers not providing adequate information on usage. A two part expanding foam filler, each of the components (tube A & tube B) had MHDS, but supplier does not supply a sheet for the foam produced by mixing these as "we don't supply or package the foam so we're not obliged to provide a MHDS." It turned out the foam was a respiritory & skin sensitiser. I'd also add that a similar lack of info on mixtures is fairly common with 2 pack paints & glues

Chris G
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#6 Posted : 20 February 2008 13:50:00(UTC)
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Posted By Edward Shyer


One reason Why one should not rely wholly on MSDS for COSHH assessments

Sodium Chloride (NaCl)

or was that Salt

Precautions:

Keep locked up.. Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective
clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away from
incompatibles such as oxidizing agents, acids.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic

Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits: Not available.


Then again that may be why there are so many bonkers conkers stories especially if professional practitioners use and follow MSDS to the letter.And this is only one aspect of the job.

Cant wait to go to my local chip shop
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#7 Posted : 20 February 2008 13:52:00(UTC)
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Posted By Chris Packham
Chris

Of course this means that the supplier is denying his responsibility as set down in section 6-1 of the Health and Safety at Work etc. Act. (see my original posting).

I frequently find that suppliers are unaware of this duty, believing that providing they have supplied the safety data sheet this is all they have to do.

When I point out to my clients' suppliers their duties under the Act the response is often one that would be unprintable here! Some then comply, others refuse (and needless to say, usually lose the business!)

It becomes even more complicated if you have two chemicals purchased from two different manufacturers and then react these. How far is each responsible? As far as I can see this is not covered in any regulation (and not even in REACH!)

Chris
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#8 Posted : 20 February 2008 14:17:00(UTC)
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Posted By Bob Youel

Additionally 'REACH' is going affecting 'CHIP' which will affect 'COSHH' so be aware as the MSDS information will be changed and tightened up

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#9 Posted : 20 February 2008 14:43:00(UTC)
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Posted By Fornhelper
I sometimes feel that when undertaking COSHH assessments we can sometimes be guilty of 'information overload' and miss the whole point of carrying out the assessment!!

Whilst I appreciate that detailed information and assessments are very often necessary, I do feel that 'COSHH' is an area where many practitioners tend to 'overegg' things and they believe that some kind of technical knowledge / chemistry background is needed. I despair when I see 'COSHH assessments' for using cleaning agents / toner ink / washing up liquid / paint etc full of details of MEL's & OELs and what to do if someone drinks or eats it!!! - not to mention the entire contents of a safety data sheet being transferred on to the assessment.

I appreciate that in industries where substantial quantities of substances are being used or specific processes are being carried out then more detailed assessments will be necessary but in a care home or a building site do we really need to know the MEL and flammability properties of 'Mr Muscle' or emulsion paint and what to do if someone digests them ???? (I've yet to see a risk assessment for using a stanley knife with 'person swallows blade' identified as a significant risk!!!)

I totally agree that it is part of our role to recognise our level of competence and say 'I need help' when necessary, but I would also submit that we shouldn't be afraid of having a COSHH assessment that says 'Wear gloves and eye protection' (sorry went immediately to 'last' control measure there!!!) without including technical data and information that means little or nothing to the employee (or the practitioner!!!) and has nothing to do with the process or task a substance is being used for.

Regards
FH
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#10 Posted : 20 February 2008 14:53:00(UTC)
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Posted By Chris Packham
FH

Yes, in principle I agree. Let us keep in simple. But how are you going to know what hazard you are facing unless you have the relevant information? I have recently seen the type of COSHH risk assessment you speak of where, because the chemistry was not understood, there had been a potentially serious incident. This involved two cleaning products, neither particularly harmful in themselves, being mixed. The result was a reaction releasing a very toxic substance. Fortunately there were no serious consequences, but this was just due to good luck.

You also suggest wearing gloves. Which gloves? How many people are even aware of permeation breakthrough? Do those that are realise that the manufacturers' published data are only guidance and not indicative of what you will achieve in practice. Recently I have had to condemn all the gloves in two workplaces as totally unsuitable for the purpose. In one case the employer had relied upon the advice from his local supplier which was totally incorrect.
Any glove recommendation must, in my view, state which glove (and not just which material) and for how long the glove may be used. In my experience over 60% of all gloves I see used for chemical protection are the wrong ones. If you need to know more on this take a look at the chapter in "Protective Gloves for Occupational Use (CRC Press, ISBN 0-8493-1558-1).

Chris
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#11 Posted : 26 February 2008 22:53:00(UTC)
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Posted By Darren Beavan
I am not a chemist but have found that COSHH assessments can come up with sensible solutions provided you spend most of your time reviewing the activities being done (incl. frequency), the quantity of substance in use and the size and type of dispensing containers. I have found once armed with such information it is much easier to extract what you need from the MSDS in respect to hazard information. Admittedly the format of the MSDS is poor and the manufacturer/supplier will try and include as many over the top controls as possible to remove liability (probably why no one has ever been prosecuted). However, if you follow the approach of the online COSHH essentials and see which data it uses you can cut through all the waffle. Personally I use a two stage assessment process (simple and complex) to ensure the assessments are fit for purpose and add value. I also always ensure that whatever information needs to be communicated to the user is presented on the first page of the assessment in a summary. I actually do this will all types of assessment as I believe it respects the way people want to deal with information today - short sharp and to the point.

Regards

Darren
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#12 Posted : 27 February 2008 07:07:00(UTC)
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Posted By Chris Packham
Darren

Caution when using systems such as COSHH essentials. I can demonstrate how you can do a risk assessment using this type of approach, which is based on risk phrases, and come up with insignificant risk, whereas in reality the opposite is true.

If you want an example of this contact me direct and I will send you a document that I produced called: "When is a safety data sheet not a safety data sheet?"

Chris
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#13 Posted : 27 February 2008 11:34:00(UTC)
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Posted By steve e ashton
Chris:

You are highlighting a serious and long standing problem. Far too many MSDS appear to be suppliers trying to duck any and all responsibility for providing sensible relevant or accurate information.

My all-time favourite was the skin cleanser / disinfectant MSDS which included the phrase 'avoid skin contact'...

Steve
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