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#1 Posted : 10 September 2008 12:05:00(UTC)
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Posted By Martin H It has just been pointed out to me that an MSDS sheet has incorrect information in it, and that the risk assessment I undertook / procedures in place are wrong. I have requested (and subsequently received) an up-to-date copy of the MSDS, and it has the same date (and therefore the same incorrect information). Should I go back and review EVERY single MSDS, or is it general practice to assume that MSDS are correct?
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#2 Posted : 10 September 2008 12:17:00(UTC)
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Posted By Chris Packham In my experience the majority of MSDS are incorrect. I haven't seen one in the past 12 months, for example, that has met the legal requirement in terms of the information required about personal protective equipment. However, in the context of a risk assessment this is irrelevant as the MSDS is not the document providing the data for a risk assessment. MSDS are only about the chemical as supplied and, as I have stated many times on this forum, only provided to comply with CHIP. The ACoP for COSHH (para 13) actually confirms this. For a risk assessment you need data on the product as used. There is a requirement in Section 6-1 of the Health and Safety at Work etc. Act 1974 for the supplier to provide this, although most are not aware of this and almost none do - until this is pointed out to them, and even then with reluctance. I see numerous risk assessments based on the MSDS that from my perspective (skin exposure) are simply wrong. So yes, you need to review your risk assessments, but based on Section 6-1 information and not on the MSDS. Obviously I cannot go into great details on the reasoning behind this, but if you need more feel free to contact me direct. Chris
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#3 Posted : 10 September 2008 12:33:00(UTC)
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Posted By Paul Leadbetter Martin The Chemical Hazard Communication Society carried out a survey a couple of years ago and, I think, showed that less than 10% (yes, 10%) of MSDSs were correct in every respect so they are not to be trusted. I do not think that the situation will improve until a company is prosecuted for providing duff information. Paul
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#4 Posted : 10 September 2008 12:43:00(UTC)
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Posted By AJM A very interesting question, I have had personal experiance of auditing a companies full MSDS sheets and couldnt agree more. It was a big company with lots of dye chemicals and it was the first time they had been audited in 15 years. I personaly cross referenced the MSDS sheets with the most upto date EH40 document and there were a few that said non hazardous but when audited it turned out they were hazardous. Its important to check all the safety phrases too i had a few that had Sensitizing chemicals but no mention was made on the MSDS. I got involved so much that i was actually driving the companies who supplied the chemicals to change their MSDS sheets and that cant be right they should be the ones doing it. So i would personally advise an MSDS audit every few years or you could end up assessing something non hazardous when in effect it could be. Regards Alan
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#5 Posted : 10 September 2008 12:48:00(UTC)
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Posted By Pete Longworth I have seen on a number of occasions 2 MSDSs for the same substance giving contradictory information depending on the supplier. You should treat the info in an MSDS with caution to say the least. A COSHH assessment can take into account some of the info on an MSDS but it will only relate to the substance. You will also need to consider the process where the substance is used and the physical nature of the substance. In the industry where I work we use subtilisin enzymes to manufacture detergents. In some processes we use the enzyme in solid form, in others we use it in liquid form. Chemically the substances are identical, but it is much more hazardous in solid form because of the possibility of inhaling air borne dusts. Similarly, the process may involve elevated pressures, temperatures etc. You can't get any of this from an MSDS.
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#6 Posted : 10 September 2008 14:05:00(UTC)
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Posted By Martin H Thank you for all your replies. I will now go back and audit all our MSDS for inaccuracies.
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#7 Posted : 10 September 2008 14:23:00(UTC)
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Posted By Haggis JM I'd also suggest comparing different countries' versions as well. In Norway all chemicals are independently analysed and assessed, we have at least one product supplied to us which shows as non-hazardous in UK but carcinogenic in Norway!
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#8 Posted : 10 September 2008 15:03:00(UTC)
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Posted By Chris Packham Martin Fine to check safety data sheets, but keep Pete's and my comments in mind when readdressing your risk assessments. There are many substances that do not have risk phrases and thus will not generally appear on the safety data sheet, but that can cause damage to health if in contact with the skin. So if you rely just on the safety data sheet there is a very significant chance that your risk assessment will be wrong! Chris
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#9 Posted : 10 September 2008 15:23:00(UTC)
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Posted By JimE Well folks you have me kakkin in me pants now..(sorry mods if I can't use that quaint terminology !!). When I sat my IOSH managing safety 4 years ago I thought the trainer covered COSHH and R/A's concerning the chemicals we use here.He is also my H&S consultant and knows well what happens here. The reason for my discomfort is that having followed this thread and other similar ones I believe all my COSHH R/A's are duff and leave me and the company wide open to claims.This is because I never knew one had to be so diligent and not trust the MSDS. I shall look very hard at them with my EH 40 close at hand. JimE
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#10 Posted : 10 September 2008 15:30:00(UTC)
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Posted By Pete Longworth Any consultant worth his salt should know that an MSDS is not a suitable and sufficient COSHH assessment. Just imagine for one moment that there was an MSDS for water. It would probably say that it was fairly innocuous. But what if it was used in the form of super-heated steam, or used in the form of ice as a cooling medium. Would the MSDS mention that prolonged contact could result in dermatitis, I doubt it.That's why your COSHH assessment must be more than just an MSDS.
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#11 Posted : 10 September 2008 15:36:00(UTC)
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Posted By JimE Pete, Yes indeed, point taken. Good job this forum exists for folks like me !!!! :) JimE
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#12 Posted : 10 September 2008 15:56:00(UTC)
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Posted By Chris Packham Jim And remember that EH40 is only for inhalation exposure. It has little relevance for skin exposure. Chris
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#13 Posted : 10 September 2008 15:56:00(UTC)
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Posted By Martin H Than you everyone - points all noted. I'm in the same position as JimE - basically I have to go back and start all over again. Just to clarify though - if something appears on the EH40 list, that overrides potentially anything that is contained in the MSDS, irrespective of product use. I have an MSDS that says "The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.", yet later on says that it contains a product listed in EH40. So I ignore the MSDS wording and review everything based on the EH40.
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#14 Posted : 10 September 2008 16:05:00(UTC)
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Posted By Chris Packham Martin It could be a question of concentration. Below a certain level (1% or 0.1% depending upon state, e.g. liquid, vapour) even a substance with a risk phrase does not have to be mentioned on the safety data sheet. It could still cause an allergic reaction in a previously sensitised person, though! If you need to know more about why the safety data sheet is not suitable for a COSHH risk assessment e-mail me and I will e-mail you back a document on this. Chris
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#15 Posted : 11 September 2008 12:12:00(UTC)
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Posted By Donk Chris can i have a copy of this document please.
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#16 Posted : 11 September 2008 12:21:00(UTC)
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Posted By Chris Packham Donk Drop me an e-mail on chris.packham@enviroderm.co.uk and I will e-mail you back a copy. Chris
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