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chas  
#1 Posted : 22 January 2013 16:52:26(UTC)
Rank: Super forum user
chas

For those involved with business continuity plans, here's a senario to get your teeth into. http://www.bbc.co.uk/news/world-europe-21147361 What if the gas is not as 'friendly' as the authorities say....I dread to think!?
jay  
#2 Posted : 22 January 2013 17:27:49(UTC)
Rank: Super forum user
jay

The yahoo news item gives better insight. http://news.yahoo.com/ga...-024755078--finance.html It may do reputational damage to one of the leading lubricant additive companies as this does not appear to be a gas leak but apparently a product that has decomposed "...........Internal operations director Pierre-Jean Payrouse said the company was battling to plug the leak, as the cloud spread over some 350 km (220 miles), but said it might take until the evening. The cause of the leak was still unknown." "It's not so much a leak as a product that has decomposed, which smells very bad and which is escaping," Payrouse told RTL radio. "An investigation is under way (into what happened) but our priority is to deal with the problem." There is a lubricant additive, Zinc dithiophosphate (ZDDP) that can decompose giving off Hydrogen Sulphide and mercaptans on heating above 80 to 90 degrees C http://en.wikipedia.org/wiki/Zinc_dithiophosphate http://en.wikipedia.org/wiki/Zinc_dithiophosphate
peter gotch  
#3 Posted : 23 January 2013 13:37:49(UTC)
Rank: Super forum user
peter gotch

It's so safe that there are lots of MSDSs on the internet.... ....and it's one of the relatively few (~850) chemicals used daily (estimated 1 million), where HSE sees it as being so safe as to assign Occupational Exposure Limits in EH40 Methyl mercaptan aka Methanethiol 0.5ppm 8hr TWA and 2ppm 15min STEL Ethyl mercaptan aka Ethanethiol 0.5ppm 8hr TWA, no STEL assigned which means that you multiply by 3 for short term excursions.
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