Keep in mind that WELs are only relevant for inhalation exposure. It is possible to be below the WEL and still have skin exposure sufficient to initiate a health reaction.
“Air threshold limits are insufficient to prevent adverse health effects in the case of contact with substances with a high dermal absorption potential.” - Drexler H, Skin protection and percutaneous absorption of chemical hazards, Int. Arch Occup. Environ. Health (2003)
DNELs are ‘derived’ exposure levels and have no real meaning when it comes to skin exposure“. Indeed, the whole topic of DNELs can be confusing. Consider the following:
“REACH legal text also states that . . . it may be necessary to identify different DNELs for each relevant human population (e.g. workers, consumers and humans via the environment) and possibly for certain vulnerable sub-populations (e.g. children, pregnant women) and for different routes of exposure.” – UK WATCH committee, Nov. 2006
So which DNEL(s) would you apply in your circumstances?
When it comes to skin…
“However, there is no scientific method of measuring the results of the body’s exposure to risk through dermal contact. Consequently no dermal exposure standards have been set.” - from “Occupational skin diseases and dermal exposure in the European Union (EU-25):policy and practice overview - European Agency for Safety and Health at Work
and
“A generally accepted method, which is able to predict the dermal absorption potential of a substance in humans, does not currently exist.” – Drexler H, Skin protection and percutaneous absorption of chemical hazards, Int Arch Occup Environ Health, 2003, 76
also
“Direct transdermal uptake from air is not routinely considered. Yet the studies outlined in the previous paragraph suggest that, for at least some indoor pollutants, direct dermal uptake from air may occur at rates that are comparable to or larger than inhalation uptake.” – Weschler CJ, Nazarofi WW, Dermal Uptake of Organic Vapors Commonly Found in Indoor Air, Environmental Science & Technology, 2014, 48, 1230-1237
Furthermore, there are several thousand chemicals that are recognised as skin sensitisers that have not been assigned either a WEL nor Hazard Statement, so will not appear as such on a safety data sheet. Indeed, they may be in the chemical you will be using but not appear on the safety data sheet at all.